Comparison between Mo BIS and Mo K-Edge Absorption Spectrum
نویسندگان
چکیده
منابع مشابه
Identification of a Mo-Fe-S cluster on NifEN by Mo K-edge extended X-ray absorption fine structure.
Absorption Fine Structure Simon J. George,† Robert Y. Igarashi,‡ Cinthia Piamonteze,† Basem Soboh,‡ Stephen P. Cramer,†,§ and Luis M. Rubio*,‡ Department of Plant and Microbial Biology, UniVersity of CaliforniasBerkeley, 111 Koshland Hall, Berkeley, California 94720, AdVanced Biological and EnVironmental X-ray Facility, Lawrence Berkeley National Laboratory, 1 Cyclotron Road, Berkeley, Californ...
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The title compound, [Mo(2)(C(5)H(5))(2)(C(12)H(11)P)(2)(CO)(4)]·C(6)H(14), is a centrosymmetric Mo complex in which two Mo atoms are connected by an Mo-Mo bond [3.2072 (12) Å]. Each Mo atom is coordinated by an η(5)-cyclo-penta-dienyl ligand, two carbonyl ligands and a diphenyl-phosphine ligand in a piano-stool fashion.
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We compare ab initio broad spectrum calculations of the K-edge X-ray absorption spectra of copper and molybdenum against accurate experimental measurements and tabulated standards on an absolute scale. Comparisons are also presented for the fine structure in the spectra. & 2010 Elsevier B.V. All rights reserved.
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The title compound, [Mo(2)(C(11)H(16)N)(4)(C(10)H(11)N)(2)], is a dinuclear molybdenum complex with a formal metal-metal bond [Mo⋯Mo separation = 2.5946 (8) Å], four anilide-type ligands and two bridging mesityl nitrile groups. There are two inversion symmetric mol-ecules in the unit cell (an inversion center is localized at the mid-point of the Mo-Mo bond), each with approximate non-crystallog...
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The asymmetric unit of the title compound, [Mo(2)(η(5)-C(5)H(5))(2)(C(22)H(29)P)(2)(CO)(4)]·2C(4)H(8)O, contains two half-mol-ecules of the organometallic species and two solvent mol-ecules. Both organometallic mol-ecules are completed by crystallographic inversion symmetry, yielding dimeric units with Mo-Mo single-bond lengths of 3.2703 (6) and 3.2548 (6) Å. Each Mo atom is also coordinated by...
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ژورنال
عنوان ژورنال: Acta Physica Polonica A
سال: 1992
ISSN: 0587-4246,1898-794X
DOI: 10.12693/aphyspola.82.329